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Herbicide
Position :玩时时彩月入100万大神> Product > Pesticides > Herbicide
Paraquat 42%TECH 240SL 200SL
 

Paraquat

Herbicide

HRAC  D WSSA  22; bipyridylium

 

 

 

NOMENCLATURE

paraquat dichloride

IUPAC name 1,1'-dimethyl-4,4'-bipyridinediium dichloride; 1,1'-dimethyl-4,4'-bipyridinium dichloride; 1,1'-dimethyl-4,4'-bipyridylium dichloride 

Chemical Abstracts name 1,1'-dimethyl-4,4'-bipyridinium dichloride 

Other names methyl viologen  CAS RN [1910-42-5];[2074-50-2] bis(methyl sulfate)  EEC no. 217-615-7  Development codes PP148; PP910 for bis(methyl sulfate) (both ICI) 

 

paraquat

Common name paraquat (BSI, E-ISO, (m) F-ISO, ANSI, WSSA, JMAF); no name (Germany)

IUPAC name 1,1'-dimethyl-4,4'-bipyridinediium; 1,1'-dimethyl-4,4'-bipyridinium; 1,1'-dimethyl-4,4'-bipyridylium 

Chemical Abstracts name 1,1'-dimethyl-4,4'-bipyridinium 

CAS RN [4685-14-7]  EEC no. 225-141-7 

 

PHYSICAL CHEMISTRY

paraquat dichloride

Composition Not normally isolated from the tech. products, which are >95% pure.  Mol. wt. 257.2  M.f. C12H14Cl2N2  Form Colourless, hygroscopic crystals.  M.p. Decomposes at c. 340 ºC  V.p. <1×10-2 mPa (25 °C)  KOW logP = -4.5 (20 °C)  Henry <4×10-9 Pa m3 mol-1 (calc.)  S.g./density 1.24-1.26 (20 ºC)  Solubility In water c. 620 g/l (20 ºC). Practically insoluble in most organic solvents.  Stability Stable in neutral and acidic media, but readily hydrolysed in alkaline media. Photochemically decomposed by u.v. irradiation in aqueous solution. 

 

paraquat

Mol. wt. 186.3  M.f. C12H14N2 

 

APPLICATIONS

paraquat dichloride

Biochemistry During photosynthesis, superoxide is generated, which damages cell membranes and cytoplasm.  Mode of action Non-selective contact herbicide, absorbed by the foliage, with some translocation in the xylem.  Uses Broad-spectrum control of broad-leaved weeds and grasses in fruit orchards (including citrus), plantation crops (bananas, coffee, cocoa palms, coconut palms, oil palms, rubber, etc.), vines, olives, tea, alfalfa, onions, leeks, sugar beet, asparagus, ornamental trees and shrubs, in forestry, etc. Also used for general weed control on non-crop land; as a defoliant for cotton and hops; for destruction of potato haulms; as a desiccant for pineapples, sugar cane, soya beans, and sunflowers; for strawberry runner control; in pasture renovation; and for control of aquatic weeds. For control of annual weeds, applied at 0.4-1.0 kg/ha. Formulation types SL.  Compatibility Incompatible with alkaline materials, anionic surfactants, and clay-containing inert materials. 

 

ANALYSIS

Product analysis by colorimetry (AOAC Methods, 17th Ed., 969.09; CIPAC Handbook, 1992, E, 166-168; 1995, G, 128); free 4,4'-bipyridyl, ibid., 1998, H, 216; in mixture with diquat, by colorimetry (CIPAC Handbook, 1992, E, 73-78; ibid., 1995, G, 49). Residues determined by colorimetry after reduction (Pestic. Anal. Man., 1979, II; A. Calderbank & S. H. Yuen, Analyst (London), 1965, 90, 99; P. F. Lott et al., J. Chromatogr. Sci., 1978, 16, 390; J. B. Leary, Anal. Methods Pestic. Plant Growth Regul., 1978, 10, 321). Residues in potatoes by rplc with dual channel u.v. detection (AOAC Methods, 17th Ed., 992.17). Details of methods available from Syngenta. 

 

MAMMALIAN TOXICOLOGY

paraquat dichloride

Reviews FAO/WHO 47, 49 (see part 2 of the Bibliography).  Oral Acute oral LD50 for rats 157-129, guinea pigs 30-58 mg/kg.  Skin and eye Acute percutaneous LD50 for rats 911 mg paraquat ion/kg. Irritating to skin and eyes (rabbits). Absorption through intact human skin is minimal; exposures can cause irritation and a delay in the healing of cuts and wounds; can cause temporary damage to nails. Not a skin sensitiser (guinea pigs).  Inhalation No vapour toxicity. Extreme exposure to spray droplets may cause nose bleeding.  NOEL (1 y) for dogs 0.65 mg/kg b.w. daily; (2 y) for rats 1.7 mg/kg b.w. daily.  ADI (JMPR) 0.004 mg/kg b.w. (as paraquat ion) [1986].  Toxicity class WHO (a.i.) II; EPA (formulation) II (oral, a.i.); III (dermal, a.i.)  EC classification T+; R26| T; R24/25, R48/25| Xi; R36/37/38| N; R50, R53 

 

ECOTOXICOLOGY

paraquat dichloride

Birds Acute oral LD50 for bobwhite quail 175, mallard ducks 199 mg/kg. LC50 (5 d) for bobwhite quail 981, Japanese quail 970, mallard ducks 4048, ring-necked pheasant 1468 mg/kg.  Fish LC50 (96 h) for rainbow trout 26, mirror carp 135 mg/l.  Daphnia EC50 (48 h) 6.1 mg/l.  Algae EbC50 (96 h) 0.10 mg/l; ErC50 0.28 mg/l.  Bees LD50 (72 h) (oral) 36 μg/bee; (contact) 150 μg/bee.  Worms LC50 >1380 mg/kg soil. 

 

ENVIRONMENTAL FATE

EHC 39 (WHO, 1984).  Animals In rats, following oral administration, 76-90% of the dose was excreted in the faeces, and 11-20% in the urine. Paraquat does not bioaccumulate, with >90% of the dose eliminated in 72 h.  Plants On plant surfaces, photochemical degradation occurs. Degradation products which have been isolated include 1-methyl-4-carboxypyridinium chloride and methylamine hydrochloride.  Soil/Environment Paraquat is rapidly degraded by soil micro-organisms (DT50 of unadsorbed paraquat <1 w). Strong binding in soil increases persistence. Paraquat is strongly bound and inactivated by soil and aquatic sediments, and does not leach into groundwater; Kd >10 000. 

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